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While the list of books is displaying click the options button in the section for the book you want to remove. Some new buttons should appear including one to "remove local copy". That will remove the file from that computer without removing the book's listing from the "library" in the nook app or your account on the B&N server. To make it disappear entirely go to your library on the B&N web site, but remember that after using "delete" instead of "archive" you will not be able to download it again without paying for it again.